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Electric dipole transition
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Electric dipole transition : ウィキペディア英語版
Electric dipole transition

Electric dipole transition is the dominant effect of an interaction of an electron in an atom with the electromagnetic field.
Following,〔http://electron6.phys.utk.edu/QM2/modules/m10/time.htm〕 consider an electron in an atom with quantum Hamiltonian H_0 , interacting with a plane electromagnetic wave
: (,t)=E_0 (,t)=B_0(t) = \frac p_z \sin \omega t. \,
Electric dipole transitions are the transitions between energy levels in the system with the Hamiltonian H_0 + W_(t) .
Between certain electron states the electric dipole transition rate may be zero due to one or more selection rules, particularly the angular momentum selection rule. In such a case, the transition is termed ''electric dipole forbidden'', and the transitions between such levels must be approximated by ''higher-order transitions''.
The next order summand in W(t) is written as
: W_(t) = \frac (L_x + 2S_x) B_0 \cos \omega t \,
and describes magnetic dipole transitions.
Even smaller contributions to transition rates are given by higher electric and magnetic multipole transitions.
==See also==

*Dipole
*Electric dipole moment
*Electromagnetism
*Magnetic dipole transition

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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